T 2441/09 (Vinyl acetate/ethylene emulsion/CELANESE INTERNATIONAL CORP.) 31-10-2013

Reasons for the Decision

1. The appeal is admissible.

In view of the outcome of these appeal proceedings on the question of inventive step (see points 2 to 5 below), it is not necessary to discuss the formal admissibility (Article 123 and 84 EPC) and novelty of the main request and of auxiliary requests 1 to 3.

2. Inventive step - main request

2.1 Closest prior art

Document (1) describes ethylene-vinyl acetate copolymer emulsions having an excellent miscibility with pigments (see page 2, first full paragraph). These emulsions are used in paints (i.e. coating compositions) (see page 2, first sentence of the second full paragraph). Furthermore, the method of production described on page 5, second paragraph shows that water is used to make the claimed polymeric composition. Example 5 of document (1) (Table 1 on page 9), which has to be read in conjunction with example 1 on page 7, describes a composition in which water (page 7, see line 7), a polymer formed from ethylene and vinyl acetate (see page 7, lines 8 to 16), a pigment (see page 7, line 21), and hydroxyethyl cellulose (see Table 1 on page 9, example 5) are present. Furthermore, a water-soluble protective colloid is also contained in the composition described in example 1 (see page 7, lines 3 to 6). The amount and the nature of this colloid can be taken from Table 1 on page 9 (see more particularly Example 5 in which the colloid is hydroxyethyl cellulose (thus a hydroxyalkyl cellulose as mentioned on page 4, middle of the second full paragraph) in an amount of 3 wt%).

Hence, the claimed subject-matter differs from the compositions disclosed in document (1) only in that the phosphate surfactant is not mentioned in example 5 of document (1).

2.2 Problem

The problem underlying the patent in suit can be seen as the provision of an emulsion having improved scrub resistance in a high PVC (pigment volume concentration) aqueous coating composition (see [0008] of the patent in suit).

2.3 Solution

The solution proposed by the patent in suit is represented by the emulsions of claim 1.

2.3.1 The board is of the opinion that the argument of appellant I (see point V above) is not convincing for the following reasons:

It is based on the results of examples 2 and 3 of the patent in suit, in which coating compositions using 84% PVC paint formulations are described and have excellent scrub resistance. Both examples 2 and 3 of the patent in suit differ from example 5 of the closest prior-art document (1) not only by the presence of the distinguishing feature but also by other features. These examples of the patent in suit contain compounds such as a biocide, potassium hydroxide and titanium oxide which are not present in the compositions described in document (1) (see Table 1). Hence, examples 2 and 3 according to the patent in suit do not represent the structurally closest approximation of example 5 of Table 1 of the closest prior-art document (1).

According to board of appeal case law, if comparative data are used to show the presence of an improved effect, the nature of the comparison with the closest prior art must be such that the alleged effect originates in the distinguishing feature of the claimed invention compared to the closest prior art. In view of the numerous differences between examples 2 and 3 of the patent in suit and Example 5 in Table 1 of document (1), it has not been shown that the alleged improved scrub resistance is due to the distinguishing feature between the claimed subject-matter and the emulsions of document (1) (see T 181/82, OJ EPO 1984, 401).

2.3.2 Appellant I submitted, in its statement setting out the grounds of appeal, that document (1) does not disclose the specific combination containing an ethylene/vinyl acetate copolymer, a phosphate functional surfactant and a protective colloid which confers excellent scrub resistance for 84 %PVC paint formulations.

As explained above, this alleged excellent scrub resistance has not been demonstrated by appellant I. As a result, the problem underlying the patent in suit has not been credibly solved. Moreover, the scrub resistance values given in Table 2 of the patent in suit for comparative examples 3A and 3C (respectively 150 and 75) are better than the one example 3F (35) according to the invention. This also casts serious

doubts on the presence of the alleged better scrub resistance over the whole scope claimed.

2.3.3 In consequence, the problem defined in point 2.2 above has not been solved and has to be reformulated as the provision of alternative emulsions to be used in paints.

2.3.4 The results summarised in Table 2 of the patent in suit show that this problem has been solved by the claimed compositions.

However, the proposed solution cannot be considered as inventive for the following reason:

The disclosure of document (l) is not limited to the values given in the examples. Knowing from the disclosure of document (1) that the ethylene-vinyl acetate copolymer emulsion has a good miscibility with pigments (see page 2, lines 4 to 5 and last two lines of the last paragraph) without impairing the properties of the polymeric emulsion, and being aware that the anionic surfactant present in example 5, namely sodium dodecylbenzenesulfonate, can be replaced by another surfactant listed on page 4, line 4 to 14, including an alkali salt of phosphoric acid alkyl ester such as sodium diethylhexyl phosphate, the person skilled in the art seeking to solve the problem defined in point 2.3.3 would replace the sodium dodecylbenzensulfonate by a phosphor-containing surfactant to arrive at the claimed invention.

2.4 An inventive step for the main request is thus not acknowledged.

3. Inventive step - first auxiliary request

3.1 Claim 1 of this request differs from claim 1 of the main request only in that the "ethylenically unsaturated monomers" are only optionally added when forming the polymer. Being optional, they cannot be considered a distinguishing feature.

3.1.1 The polymer according to claim 1a) of the first auxiliary request is predominately (>85%) or entirely composed of ethylene and vinyl acetate. However, in view of the fact that the compositions of document (1) comprise polymers consisting of ethylene and vinyl acetate (see point 2.1 above), the same reasoning as for the main request is applicable (see point 2.3.4), with the consequence that the claimed subject-matter is not inventive.

4. Inventive step - second auxiliary request

4.1 As explained above (see point IV), claim 1 of this request differs from the subject-matter of the main request in that the colloid has been limited to hydroxyethyl cellulose.

4.1.1 Limiting the protective colloid to a colloid already mentioned in document (1) does not render the claimed matter inventive. The reasoning of point 2.3.4 is also applicable to this request, with the consequence that this request does not fulfil the requirement of Article 56 EPC.

5. Inventive step - third auxiliary request

5.1 The subject-matter of claim 1 of the third auxiliary request differs from claim 1 of the main request in that the amounts of copolymer binder and protective colloid in the coating compositions have now been introduced and in that a specific percentage of pigment has been added into the coating composition.

5.1.1 In the absence of any meaningful comparative data, the problem underlying the patent in suit can only be seen as the provision of alternative coating compositions to be used in paints.

5.1.2 In the compositions described in document (1), the amount of the copolymer ethylene/vinyl acetate is not limited and the amount of protective colloid ranges from 0.3 to 4 wt% (see claim 1 on page 1 of document 1), thus overlapping with the range mentioned in claim 1 of this request. Moreover, the amount of pigment to be added to the emulsions of document (1) is also not limited to any specific value. Therefore, the skilled person, being aware of the disclosure of document (1), would vary the amount of these different constituents to arrive at the claimed coating compositions without any inventive skill. Furthermore, in view of the disclosure of document (3), for the person skilled in the art, selecting the appropriate proportions of the different constituents would be a trade-off between the paint's expected improved scrub resistance and reduced hiding ability when the PVC is decreased (see document (3), column 2, lines 3 to 18).

5.2 The third auxiliary request therefore lacks inventive step.