T 0016/04 (PAP-based dishwashing composition/DIVERSEY) 23-11-2005

Reasons for the Decision

1. The Board is satisfied that the subject-matter of the claims of the patent as granted is novel and that the patented invention is sufficiently disclosed. Since the Appellant has not contested the positive findings of the Opposition division in these respects, no reasons need to be given.

2. Inventive step (Article 100(a) EPC in combination with Articles 52(1) and 56 EPC): claim 1

2.1 The detergent composition for machine dishwashing defined in claim 1 as granted (see above point II of Facts and Submissions) produces upon a certain dilution in water a pH from 6 to 9 and comprises effective amounts of PAP and of a bleach-resistant amylase (characterized by a certain half-life in the presence of PAP), in combination with 1 to 75% by weight of a builder.

In view of paragraphs 6, 9, 10 and 31 it is apparent that this composition aims at achieving an "excellent" level of both TR and SR from soiled dishware in machine dishwashing.

2.2 According to the established jurisprudence of the Boards of Appeal (see, for instance, The Case Law of the Boards of Appeal of the EPO, 4th Edition 2001, I.D.3.3), the prior art representing the starting point for the assessment of inventive step according to the problem-solution approach should relate to the same or to a similar technical problem as the patent in suit.

2.2.1 The Board notes that the skilled person is undisputedly aware that detergent compositions of the prior art comprising bleach-resistant amylases and bleaching agents should have excellent levels of TR and SR in combination. As a matter of fact, dishwashing compositions comprising bleach-resistant amylases (such as those disclosed in D1, D3, D13 and D14) have been specifically developed with the aim to avoid the decrease of amylase activity known to occur when effective bleaching agents are added to the standard amylases.

The Board notes additionally that even the inventors of the patent in suit have explicitly made reference to this prior art as disclosed in D3, D13 and D14 (see paragraphs 5 and 21 of the patent in suit).

However, the patent in suit also states in paragraph 5 that "it has been observed that the mere replacement of standard amylases with the bleach-resistant varieties in conventional formulations resulted in poorer, rather than improved, overall performance". Since this statement is given without any reference to specific previous publications it is not clear if it reflects information available only to the Respondent itself or rather to some background knowledge of the skilled person.

Nevertheless, the Board notes that in particular D3 aims at further improving the amylolytic activity displayed by bleach-resistant amylases during dishwashing in the presence of bleaching agents. This is expressly indicated at page 1 of D3, lines 11 to 21, stating that:

"It has been found that the activity level and the stability in the presence of oxidizing agents of the prior art mutant amylases is open to improvement, and thus the purpose of this invention is the provision of a mutant alpha-amylase with an improved activity level and improved stability in the presence of oxidizing agents in comparison to the prior art mutant amylases. In this context the term "stability in the presence of oxidizing agents" refers … to the stability in the washing solution or dishwashing solution during the washing process or dish washing process…"(emphasis added by the Board). Moreover, this citation also discloses the possible presence of standard hypochlorite generating or peroxy bleaching agents in the dishwashing detergent compositions (see page 5, line 1, and page 6, lines 13 to 21).

Therefore, even if the skilled person would actually be aware (as possibly implied by paragraph 5 of the patent in suit) that the level of SR provided by the detergent compositions of D3 would not be satisfactory, he would still necessarily consider the detergent compositions disclosed in this citation as representative of the prior art providing the highest level of SR and TR in combination.

Hence, the Board concludes that the dishwashing detergent compositions containing bleach-resistant amylases and bleaching agents disclosed in D3 represent the best performing prior art addressing substantially the same technical problem of the patent in suit. Hence, they represent the reasonable starting point for the assessment of inventive step.

2.2.2 The Appellant in its grounds of appeal has instead started from the prior art disclosed in D11.

However, the Board finds this not appropriate, because this citation is focused exclusively on avoiding silver tarnishing and, possibly, on the use of environmentally friendly compositions (see in D11, for instance, page 1, lines 5 to 10, in combination with, lines 29 to 34 of the same page, and with the disclosure from page 2, line 18 to page 3, line 18). Therefore, D11 is not dealing with the same technical problem as the patent in suit.

Moreover, the skilled reader of D11 would also consider that this citation mentions the optional use of amylases in general (see the paragraph bridging pages 25 and 26) and quotes as only specific example thereof a standard amylase, i.e. Termamyl® (see page 26 line 5). Therefore, not only D11 is silent on the possibility of using specifically bleach-resistant amylases, but discloses to the skilled person exclusively anti-tarnishing compositions containing strong bleaching agents and standard enzymes, i.e. compositions necessarily displaying an expectedly very low amylase activity.

Accordingly, a skilled person, who aims at an excellent TR and SR in combination and who is undisputedly aware that bleach-resistant amylases have been specifically disclosed to be more active than standard amylases in bleach-containing dishwashing compositions, (i.e. by the prior art disclosed e.g. in D3) would not start from the dishwashing detergent compositions disclosed in D11 for their anti-tarnishing properties and which are expected to provide low SR.

2.3 D3 provides only a generic definition of the detergent compositions comprising the bleach-resistant amylases. Moreover, since this citation does not mention PAP and indicates as suitable any pH of the washing liquor between 7 and 11 (see page 4, line 29), it is evident that the patented composition differs from this prior art in that

(a) PAP is selected as bleaching agent and

(b) the pH range of 6 to 9 of the aqueous solution of the composition is different from (although largely overlapping with) the pH rage present in the aqueous solutions of the detergent compositions of D3.

2.4 According to the patent in suit, these features distinguishing the patented compositions from those of D3 produce an improvement of amylase activity (see, in particular, in paragraph 6 "… certain bleaches, bleach bleach-resistant enzymes, builders and wash conditions have actually been found to enhance enzyme activity and improve enzyme stability…" in connection with e.g. paragraph 85 "Unexpectedly, the amylolytic activity of the formulation containing the alpha-amylases according to the invention was synergistically enhanced by addition of the peracid at a pH of 8.5…"; and with Table 6 wherein the amylase activity of the examples containing the bleach-resistant amylase according to the invention, i.e. Duramyl®, and PAP is superior to that of the PAP-free sample based on Termamyl®). The patent in suit therefore demonstrates that the level of amylase activity achieved by the patented detergent composition is even superior to that produced by a standard amylase, e.g. Termamyl®, in the absence of any bleaching agents.

2.4.1 The Board also finds that, as correctly observed already by the Opposition division (see above point IV and page 9 of the decision under appeal, lines 9 to 24), the Appellant has failed to present any evidence or reasoning depriving of credibility the superior SR that the patent in suit attributes to the composition of claim 1. Nor has the Appellant presented in the appeal proceedings further arguments in this respect.

Hence, the Board has no reason for doubting the statements in the patent in suit that the selection of PAP and of a pH of the aqueous dishwashing solution of 6 to 9 produces a level of SR superior to that achieved by the compositions of the prior art disclosed in D3 even in the absence of any bleaching agent.

2.4.2 The Board therefore comes to the conclusion that the subject-matter of claim 1 has credibly solved vis-à-vis the dishwashing detergent compositions of the relevant prior art the technical problem of simultaneously achieving in dishwashing excellent TR (i.e. that produced by strong bleaching agents) in combination with an improved level of SR (i.e. even superior to that obtainable by amylases in the absence of any bleaching agents).

2.5 Since the available documents disclose only that the activity of enzymes in dishwashing solutions is negatively affected by bleaching agents, the skilled person has no reason to expect that the activity of the bleach-resistant amylases in the dishwashing solutions of the detergent compositions of D3 could be improved by replacing with PAP the other bleaching agents used therein.

Hence, the Board concludes already for this reason that the PAP-containing dishwashing detergent composition of claim 1 of the patent in suit provides a non-obvious solution to the technical problem posed.

2.6 The Board wishes additionally to stress that even if one hypothesises (for the sake of an argument in favour of the Appellant), that the skilled person would have started from the prior art disclosed in D11 (which in fact he would not have done, see above point 2.2.3), still the improved SR provided by the patented composition would be relevant for the definition of the technical problem credibly solved, also vis-à-vis these anti-tarnishing compositions of the prior art. Therefore, in this hypothetical case, the existing technical problem vis-à-vis the prior art disclosed in D11 would not be "to select enzymes which have improved stability in the bleach-containing composition" of this prior art (see grounds of appeal, paragraph 14 and also paragraph 19; it should be noted that by this language an element of the technical solution is inadmissibly incorporated into the definition of the technical problem), but rather the same already identified above vis-à-vis the prior art disclosed in D3 (see point 2.4.3). Since the bleach-resistant amylases are only known to perform in the presence of bleaching agents less well than standard amylases in the absence of bleaching agent, the skilled person starting from D11 could not expect that the desired improved level of SR could be achieved despite the presence of bleaching agents, by simply replacing the standard amylases by the bleach-resistant ones.

Thus, even starting from the prior art disclosed D11 the skilled person would not have arrived at the composition claimed without exercising inventive ingenuity.

2.6.1 The Appellant has also maintained that the skilled person aiming at solving the technical problem according to the above-reported definition given in paragraphs 14 and 19 of the grounds of appeal would have in any case added bleach-resistant amylases - such as those disclosed in any of D3, D13 and D14 - to the dishwashing detergent compositions of D11. It has referred to the jurisprudence of the Boards of Appeal identified above in point VI and argued that the superior level of SR achieved by the composition claimed vis-à-vis dishwashing compositions free from bleaching agents would only be a "bonus effect", wholly irrelevant for the assessment of inventive step.

2.6.2 The jurisprudence of the Boards of Appeal has indicated that a technical effect of a claimed invention may be considered a "bonus effect" only when the skilled person has no alternative other than arriving at the claimed subject-matter in order to solve another reasonable technical problem (see, for instance, the "one-way street" situation described in decision T 192/82, OJ EPO 1984, 415, also mentioned in the section of the Case Law of the Boards of Appeal of EPO, 4th Edition 2001, cited by the Appellant).

The Appellant did not demonstrate that here such a "one-way street" situation exists. Even if for the sake of argument one accepted as a technically reasonable aim the argument formulated in paragraphs 14 and 19 of the grounds of appeal (see above point 2.6) and, thus, considered it as obvious to add bleach-resistant amylases to the dishwashing detergent compositions disclosed in D11, still he could, rather than using the bleach-resistant amylases of D3, D13 or D14, equally use e.g. the bleach-resistant amylase of D1 (which has not been demonstrated to display the half-life required in present claim 1, see point 1 of the decision under appeal not contested by the Appellant) and, thus, would not arrive at the composition claimed. Moreover, he also could, rather than adding bleach-resistant amylases to the dishwashing detergent compositions disclosed in the specific examples in D11 containing PAP and whose aqueous solutions produce a pH of e.g. 8.5 to 8.8, equally add them to those PAP-containing examples of D11 wherein the pH is 11 (see in examples 5 the samples with anti-tarnishing compounds 2 or 4 of table 9; or example 6; or in examples 13 the samples with anti-tarnishing compounds 2 to 4 of table 20; or those with compounds 2 or 4 in table 21, example 14) or to those examples of D11 containing perborate or peracetic acid (see examples 1 and 3; samples A or B of Tables 7 or 13). Also in all these other cases the skilled person would not arrive at the composition claimed. Hence, the presence of these alternatives demonstrates that in the present case no so called "one-way street" situation is at hand. Consequently, the Appellant's argument fails that the improved SR achieved by the patented composition amounts to a "bonus effect" which should be disregarded when evaluating inventive step.

2.7 Therefore, the Board finds that the subject-matter of claim 1 is based on an inventive step and, thus, complies with the requirements of Article 56 EPC.

3. Inventive step (Article 100(a) EPC in combination with Articles 52(1) and 56 EPC): claims 2 to 15

The reasoning given above in respect of the subject-matter of the independent claim 1 applies also to the preferred embodiments thereof defined in claims 2 to 10.

Since the machine dishware cleaning method defined in claims 11 to 15 is based on the application of the detergent composition of claim 1, the subject-matter of these claims is found to comply with the requirements of Article 56 EPC for the same reasons given above.